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bx488@torfree.net (Andrew Wolf) wrote: >Hello, >I hope this is an appropriate post. I have just started using a FAA with >C2H2/N2O for Sr analysis. I am getting an enormous >buildup of black soot(?). Approximately a 1mm thick by 10mm high wall on >either side of the burner head opening forms in approximately 30 mins. >Eventually the flame becomes unstable and makes a loud noise, presumably >due to clogging. This occurs during warmup while aspirating water. I >understand some buildup is normal, but this seems excessive. I would >appreciate any suggestions. >Sincerely, >Andrew Wolf It sounds like you are missing baffles in gas mixing chamber and gases are being in completely mixed. I used air acetylene only for alkaline earth metal bt load sample heavily with lanthanum instead of using nitrous acetylene best of luck Bob MolonyReturn to Top
I am a user. From time to time I have to connect a chromatograph to a DCS (distributed control system). There is no way I can get involved in the details of communications systems. My specs are simple: a) signal type must be RS-232 or 485(?) b) protocol must be Modbus. period. I don't run a driver training school. This applies to both the DCS, PLC, chromatograph, whatever. Some of the vendors, i.e. non-Modicon PLCs with their own in-house solution, don't like this, but they always comply since they know that if they don't, they're not on the bid list. Even so, during system testing, I can usually allow for a full week with the assistance of the analyzer vendor to get communications working properly. One common problem is that the vendor tells us something like, "Word 13 gives the error flag." It turns out that word 13 is a composit of 16 bits. Some combinations indicate errors, others indicate which channel is scanning. I have to disassemble this in the DCS. I might add that a DCS is not intended for bit slicing. Another silly problem is that the vendor arranges the stream components in a different order than he said he would. The computer types think that when the bits come through, communications is established. Like the post office thinks that if the letter is put in the right mailbox, communications is done. Unfortunately both the sender and the receive speak different dialects of a foreign tongue. To test these, I ask the vendor something like, "Give me 123 ppm of ethylene." What happens next is that the methane indicator jumps to 24%. "Oops!" says the vendor rep. "I think Bob switched the channels here. Let me show the real sequence." And so the week goes by. I suppose the problemn is that when everything is progammable, it is impossible to know in advance what the supplier is going to do. They make it up at the last minute because it is easy. I, on the other hand, must have my recieving equipment pre-programmed to accept the signals from analyzers, vibration monitors, SCADA systems, PLCs of half a dozen vendors. Every time I do this, I have a different mix of vendors. From one job to the next, their technology changes. They make it up as they go along and their documentation is incomplete and often in error. "Oh, we've changed that. Let me FAX you the new stuff." Since they work with one piece of equipment full time, they cannot understand that what they are doing is not at all obvious to someone who is seeing it for the first time in his life. In the meantime I am at a DCS staging center 1000 miles from home living on expense account. Steak dinners, drinks, etc. are wearing me down. Its a rough life but somebody has to live it. Thats why they pay me the big bucks. By the way, you mention PC, Mac, etc. Big plants still use DCS and PLCs. Walter C. Driedger, P. Eng. 403-234-4955 In articleReturn to Top, 7397@mne.net says... > >I am writing an article on process analyzer communications. >The focus of the article is communications between the analytical >instrument (process GCs, mass specs, photodiode array, FT IR, etc.,), >the analyzer data, the plantwide data highway, system, and the >process control computers. >Whether you are a vendor or user, could you share your experiences >with the magazine's readers by answering the questions below? >1. What is the problem with analyzer communications right >now? >2. How is the analyzer communications issue relate to >standard >analyzer outputs, ie, analytical signal and signals related to >instrument operation? >3. What different communications protocols are out there? >4. Why are they different? Is there a standard? >5. What do these protocols do/attemtpt to do? >6. Why choose one over the other? >7. What kinds of devices are necessary to utilize these > protocols? >8. What kinds of analyzers can be interfaced to these >devices? >9. What kinds of output do these devices accept from the > analyzer? >10. What kind of output do they transmit and to where? >11. What benefits can users expect for each device/protocol? > >14. What are the computing requirements for using t hese devices, >ie, PC/Mac, Unix, or some othe proprietary architecture? >15. Are these devices/protocols plug and play? >16. Who is using? Names and phone numbers? (Please provide your >name phone and fax numbers, corporate affiliation, and title so I can >contact for more information or if I have questions. Please let me >know if I can quote you, too. >Thanks for your help. > Mark Weiss
bx488@torfree.net (Andrew Wolf) writes: >I hope this is an appropriate post. I have just started using a FAA with >C2H2/N2O for Sr analysis. I am getting an enormous >buildup of black soot(?). Approximately a 1mm thick by 10mm high wall on >either side of the burner head opening forms in approximately 30 mins. I would suggest you use less acetylene and more N2O. David Doff Trinity College DublinReturn to Top
"From: tmagi@onramp.net Date: Fri, 06 Dec 1996 01:47:57 GMT Message-ID: <587u2k$a5o@news.onramp.net> I need help!! how many helium molecules are there in one cubic centimeter at standard pressure (one atmosphere) at 72 deg F.?? Any help or reference would be appreciated!" This is a simple exercise that you could almost certianly do yourself, and learn something in the process. The onedatum you need to know is Avagadro's number. You can find anything you need to do the calculation in ANY basic chemistry text. Your question has nothing in particular to do with spectroscopy. Marvin MargoshesReturn to Top